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How do you make hydrogen from ammonia?

Published in Ammonia Cracking 2 mins read

Hydrogen is made from ammonia by decomposing it into hydrogen and nitrogen using a process called ammonia cracking, typically carried out in a specialized unit known as an ammonia cracker.

The Ammonia Cracking Process

The process relies on the controlled breakdown of ammonia (NH₃) molecules into their constituent elements, nitrogen (N₂) and hydrogen (H₂).

Here are the key steps involved based on the reference provided:

  • Heating Ammonia: First, the ammonia is heated until it evaporates, transforming it into a gaseous state. This prepares the ammonia for the decomposition reaction.
  • Feeding into the Reactor: The gaseous ammonia is then fed into a reactor.
  • Catalytic Splitting: Inside the reactor, ammonia splitting takes place catalytically. This means a catalyst is present to speed up and facilitate the decomposition reaction:
    2NH₃ → N₂ + 3H₂
  • Operating Conditions: The catalytic splitting process is typically conducted under specific conditions to ensure efficient conversion:
    • Temperatures: Usually runs at temperatures of 600-900 °C.
    • Pressure: Operates at a pressure of 20-40 bar.

This process yields a mixture of hydrogen and nitrogen gases, from which the hydrogen can then be separated for various applications.

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