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How do electrons behave in covalent bonds?

Published in Chemical Bonding 3 mins read

In covalent bonds, electrons are shared between atoms. Here's a breakdown of how they behave:

Sharing is Caring: The Basics of Covalent Bonds

Covalent bonds form when atoms share electrons to achieve a stable electron configuration, typically a full valence shell. Instead of transferring electrons as in ionic bonds, atoms contribute electrons to a shared pair.

  • Electron Contribution: Each atom involved in the bond contributes one electron to form a shared pair.
  • Effective Electron Gain: Though shared, the electrons are effectively associated with both atoms. This means each atom feels like it has gained an electron, enabling them to satisfy their octet rule (or duet rule for Hydrogen), which they need to be stable.
  • Number of Shared Pairs: Atoms share the exact number of electron pairs needed to complete their valence shells. For most elements, this means achieving eight electrons in their outermost shell.

Examples of Covalent Bonds

Let’s look at some simple molecules to understand better:

  • Hydrogen (H2): Two hydrogen atoms, each having one electron, share those two electrons. This completes the duet rule for both hydrogen atoms.
  • Water (H2O): One oxygen atom shares two electrons each with two hydrogen atoms. The oxygen contributes two electrons and the hydrogen atoms each contribute one electron. This way oxygen has eight electrons and each hydrogen atom has two electrons, achieving stable configuration.
  • Methane (CH4): A carbon atom, with four electrons in its outer shell, shares one electron with each of the four hydrogen atoms. The carbon contributes four electrons and the hydrogen atoms each contribute one electron. This way carbon has eight electrons and each hydrogen atom has two electrons, achieving stable configuration.

The Dance of Shared Electrons

The electrons involved in a covalent bond are not static; they are constantly in motion, attracted to the nuclei of both atoms. This constant movement is key to the bond's stability.

Key Points

Here is a summary of key points:
| Feature | Description |
| :--------------- | :------------------------------------------------------------------------------------------------------------------------------------- |
| Electron Sharing | Electrons are not transferred but shared between atoms. |
| Contribution | Each participating atom donates one electron to form a shared pair. |
| Effective Gain | Each atom involved in the bond gains an effective electron, helping them complete their valence shell. |
| Stability | The sharing of electrons results in a stable configuration for each atom, filling their outer shell and reducing overall energy. |

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