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How to Calculate the Atomic Mass of Nitrogen?

Published in Chemistry Basics 2 mins read

The atomic mass of nitrogen is approximately 14.01 atomic mass units (amu). This is the weighted average of the masses of all the naturally occurring isotopes of nitrogen.

Here's a breakdown of how this value is determined:

  • Understanding Atomic Mass: Atomic mass is the mass of an atom, typically expressed in atomic mass units (amu) or Daltons (Da).

  • Nitrogen Isotopes: Nitrogen primarily exists as two isotopes:

    • Nitrogen-14 (14N): Contains 7 protons and 7 neutrons. It's the most abundant isotope.
    • Nitrogen-15 (15N): Contains 7 protons and 8 neutrons. It's a much less abundant isotope.
  • Isotopic Abundance: The key is to know the abundance of each isotope in a natural sample of nitrogen. Typically:

    • 14N accounts for approximately 99.636% of naturally occurring nitrogen.
    • 15N accounts for approximately 0.364% of naturally occurring nitrogen.
  • Calculation: The atomic mass is calculated as a weighted average of the masses of the isotopes. Assuming the mass of 14N is approximately 14 amu and the mass of 15N is approximately 15 amu, the calculation is:

    Atomic Mass = (Abundance of 14N Mass of 14N) + (Abundance of 15N Mass of 15N)

    Atomic Mass = (0.99636 14 amu) + (0.00364 15 amu)

    Atomic Mass ≈ 13.949 + 0.055

    Atomic Mass ≈ 14.004 amu

  • Therefore, the atomic mass of nitrogen is approximately 14.01 amu. This value is usually found on the periodic table.

Important Note: The molar mass of nitrogen, which is the mass of one mole of nitrogen atoms, is approximately 14.01 grams/mole. This value is numerically the same as the atomic mass but has different units.

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