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Is H2O a good acid?

Published in Chemistry Basics 2 mins read

No, H2O (water) is not considered a good acid. Pure water is essentially neutral, possessing neither strongly acidic nor strongly basic properties.

While water can act as both an acid and a base, this behavior is very limited and occurs in a process called autoionization.

Autoionization of Water

Water molecules can react with each other in a process called autoionization:

H₂O(l) + H₂O(l) ⇌ H₃O⁺(aq) + OH⁻(aq)

In this reaction:

  • One water molecule acts as an acid, donating a proton (H⁺) to another water molecule.
  • The water molecule that gains a proton becomes a hydronium ion (H₃O⁺).
  • The water molecule that loses a proton becomes a hydroxide ion (OH⁻).

However, this reaction occurs to a very small extent. At 25°C, the concentration of hydronium ions [H₃O⁺] and hydroxide ions [OH⁻] in pure water is only 1.0 x 10⁻⁷ M. This equal concentration of [H₃O⁺] and [OH⁻] is what defines neutrality. A good acid would have a much higher concentration of H₃O⁺.

Why Water is a Poor Acid

  • Weak Proton Donor: Water is not a strong proton donor. It does not readily lose a proton to form hydroxide ions (OH⁻).
  • Equilibrium Lies to the Left: The equilibrium of the autoionization reaction strongly favors the reactants (water molecules). Very few hydronium and hydroxide ions are formed.
  • Amphoteric Nature: Water is amphoteric, meaning it can act as both an acid and a base. This duality contributes to its overall neutral character. A strong acid typically only acts as an acid.

In conclusion, while water can participate in acid-base reactions, it is not a good acid due to its very weak tendency to donate protons. It's considered neutral because the concentration of hydronium and hydroxide ions are equal.

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