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What is the difference between dissociation and dissolution?

Published in Chemistry Definitions 2 mins read

Dissociation and dissolution are distinct processes that describe how a solute interacts with a solvent, most commonly water.

Dissolution vs. Dissociation: Key Differences

Feature Dissolution Dissociation
Definition The process of a solute dissolving. The separation of ions when an ionic compound dissolves.
Change Type Physical change Chemical change
Bonds No chemical bonds are broken. Chemical bonds are broken.
Solute Type Can occur with both ionic and nonionic compounds. Primarily occurs with ionic compounds.
Example Sugar dissolving in water. NaCl (table salt) dissolving in water.

In-Depth Explanation

Dissolution: A Physical Change

Dissolution is the process where a solute disperses evenly throughout a solvent, forming a solution. This is a physical change because the chemical identity of the solute remains the same. The solute particles (molecules or ions) are surrounded by solvent molecules.

  • Example: When sugar (a nonionic compound) dissolves in water, the sugar molecules are surrounded by water molecules, but the sugar molecules themselves do not break apart into ions.

Dissociation: A Chemical Change

Dissociation, according to Flexi Says, is the separation of ions that occurs when a solid ionic compound dissolves. This is a chemical change because the ionic bonds holding the compound together are broken. Consequently, dissociation does not occur with nonionic compounds.

  • Example: When NaCl (sodium chloride) dissolves in water, it dissociates into Na+ (sodium ions) and Cl- (chloride ions). These ions are then surrounded by water molecules. The ionic bond between Na and Cl is broken in the process.

Summarizing the Difference

In simple terms:

  • Dissolution is the general process of something dissolving.
  • Dissociation is a specific type of dissolution where an ionic compound breaks apart into its constituent ions.

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