Reusable hot packs work through a process involving a supersaturated solution, typically of sodium acetate, that crystallizes when triggered, releasing heat. This process is also reversible, allowing the hot pack to be reused.
Here's a breakdown of how they work:
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Supersaturated Solution: The hot pack contains a solution with more sodium acetate dissolved than would normally be possible at room temperature. This is a metastable state. Think of it like water vapor way above 100°C - it wants to turn to liquid water, but needs a "seed" to start the process.
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Activation Disc: Inside the pack is a small metal disc, usually stainless steel. Flexing this disc creates a nucleation site. This provides the "seed" or starting point for the crystallization process.
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Crystallization and Heat Release: When the disc is flexed, it initiates crystallization of the sodium acetate. As the sodium acetate molecules arrange themselves into a crystalline structure, they release energy in the form of heat. This is an exothermic reaction.
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Recharging the Hot Pack: After use, the hot pack becomes solid and no longer generates heat. To reuse it, you need to redissolve the sodium acetate crystals. This is done by placing the hot pack in boiling water. The heat from the boiling water causes the crystals to dissolve, reforming the supersaturated solution. Once the crystals are completely dissolved, and the pack is allowed to cool, it is ready to be used again.
In essence, the hot pack stores energy in the form of a supersaturated solution and releases it as heat when crystallization is triggered. The boiling process adds energy to the system, dissolving the crystals and resetting it for another use.