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What is the valence of phosphorus?

Published in Chemistry 2 mins read

The valence of phosphorus is typically considered to be 5.

Phosphorus (P) is a group 15 element, also known as a pnictogen, with an electronic configuration of [Ne] 3s² 3p³. This means it has 5 valence electrons in its outermost shell.

  • Valence Electrons and Bonding: Phosphorus utilizes its 5 valence electrons to form a variety of chemical bonds. It can achieve a stable octet (8 electrons in its outermost shell) by:

    • Sharing these electrons in covalent bonds.
    • Accepting electrons to form ionic bonds (though this is less common for phosphorus).
  • Common Oxidation States: Due to having 5 valence electrons, phosphorus exhibits multiple oxidation states including -3, +3, and +5. The +3 and +5 oxidation states are the most common.

  • Examples of Phosphorus Compounds:

    • Phosphorus(V) oxide (P₂O₅): In this compound, phosphorus exhibits a valence of 5.
    • Phosphorus(III) chloride (PCl₃): Here, phosphorus has a valence of 3.
    • Phosphine (PH₃): In this compound, phosphorus has a valence of 3.

In summary, while phosphorus can exhibit different valences depending on the compound it forms, its most typical and stable valence is 5, reflecting its 5 valence electrons.

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