Copper is purified through an energy-intensive electrolytic process using an electrolytic cell. Here's a breakdown of the process based on the provided reference:
Electrolytic Refining of Copper
The process relies on electrolysis, separating copper from its impurities. This is achieved through the use of an electrolytic cell consisting of two key components:
- Anode: Impure copper serves as the anode.
- Cathode: A thin sheet of pure copper acts as the cathode.
The process involves the following steps:
- Electrolyte: The anode and cathode are immersed in an electrolyte solution, typically copper sulfate (CuSO₄).
- Electrolysis: When an electric current is passed through the cell:
- At the anode, copper atoms from the impure copper lose electrons and dissolve into the electrolyte solution as copper ions (Cu²⁺).
- At the cathode, copper ions (Cu²⁺) from the electrolyte gain electrons and deposit as pure copper atoms onto the pure copper sheet.
This process selectively transfers copper from the impure anode to the pure cathode, resulting in a purified copper cathode. Impurities from the anode either dissolve in the electrolyte or settle at the bottom of the cell as "anode sludge," which can be further processed to recover valuable metals.
Summary: Electrolytic refining is an effective method for purifying copper, using electrolysis to transfer copper ions from an impure anode to a pure copper cathode.