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How to Increase Cell Potential?

Published in Electrochemistry Fundamentals 2 mins read

Increasing the cell potential in an electrochemical cell can primarily be achieved by manipulating the concentrations of reactants and products.

Understanding Cell Potential

Cell potential, also known as voltage, is the driving force behind an electrochemical reaction. It determines the extent to which a reaction will proceed spontaneously. Several factors can influence it, but concentration is a key aspect that can be directly controlled.

Concentration and Cell Potential

According to the provided reference, a higher concentration of reactants leads to a higher cell potential. This is because:

  • Faster Reaction Rate: A higher concentration of reactant moves the reaction in the forward direction at a higher pace.
  • Increased Voltage Difference: The increased pace results in a higher voltage.

Practical Ways to Increase Cell Potential via Concentration

Here's how you can practically increase cell potential by manipulating concentrations:

  • Increase Reactant Concentration: Increasing the concentration of the reactants will generally shift the equilibrium towards the products, thereby increasing the cell potential.
  • Decrease Product Concentration: Decreasing the concentration of the products will also shift the equilibrium towards the products, increasing the cell potential.

Example:

Consider a simple electrochemical reaction:

A + B <=> C + D

To increase the cell potential for this reaction, you could:

  1. Increase the concentrations of A and B.
  2. Decrease the concentrations of C and D.

Summary Table: Concentration's Impact on Cell Potential

Factor Effect on Cell Potential Explanation
Increased Reactant Concentration Increase Shifts equilibrium towards products, driving the reaction forward more strongly.
Decreased Product Concentration Increase Shifts equilibrium towards products, favoring the forward reaction.

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