Copper electrolysis involves using an electric current to dissolve copper from one electrode (the anode) and deposit it onto another (the cathode). Here's a breakdown of the process:
Electrolytic Setup and Process
Here's how to perform copper electrolysis, based on the provided information and standard procedures:
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Prepare the Electrolyte:
- Use a dilute aqueous solution of copper sulfate (CuSO4) and sulfuric acid (H2SO4) as the electrolyte. Sulfuric acid increases the conductivity of the solution.
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Electrodes:
- Anode: Use a copper electrode (e.g., a penny, as referenced). This is connected to the positive terminal of the power source. The copper anode will dissolve into the electrolyte as copper ions.
- Cathode: Use another conductive material (e.g., another piece of copper or a different metal). This is connected to the negative terminal of the power source. Copper ions from the electrolyte will deposit onto this electrode, increasing its mass and coating it with copper.
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Power Source:
- Use a 9-volt (V) battery (as referenced) or a DC power supply. Ensure it provides a stable and appropriate current for the electrolysis process.
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Electrolysis Process:
- Submerge both electrodes in the electrolyte, ensuring they do not touch each other to prevent a short circuit.
- Connect the anode to the positive (+) terminal and the cathode to the negative (-) terminal of the power source.
- When the electric current is applied, the following reactions occur:
- At the Anode (Oxidation): Copper atoms (Cu) are oxidized, losing two electrons to form copper ions (Cu2+). The reaction is: Cu(s) → Cu2+(aq) + 2e-. The reference mentions that "copper atoms are oxidized to form cations with a positive charge (Cu2+)".
- At the Cathode (Reduction): Copper ions (Cu2+) in the electrolyte are reduced, gaining two electrons to become solid copper (Cu). The reaction is: Cu2+(aq) + 2e- → Cu(s).
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Observation:
- You should observe the anode gradually dissolving as copper is transferred into the electrolyte as Cu2+ ions.
- The cathode should increase in mass as copper ions from the electrolyte are deposited onto its surface as solid copper.
- The electrolyte solution may change color slightly as the concentration of copper ions changes.
Summary Table
Component | Function | Reaction |
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Anode | Copper source, undergoes oxidation | Cu(s) → Cu2+(aq) + 2e- |
Cathode | Where copper is deposited, undergoes reduction | Cu2+(aq) + 2e- → Cu(s) |
Electrolyte | Conducts ions, contains Cu2+ ions | Aqueous solution of CuSO4 and H2SO4 |
Power Source | Provides electric current | 9V Battery (as example) |