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How do you calculate molar flow rate of gas?

Published in Flow Rate Calculations 3 mins read

The molar flow rate of a gas is calculated by dividing the mass flow rate by the molar mass of the gas.

Here's a detailed breakdown of how to calculate the molar flow rate of a gas, including the relevant information from the provided reference:

Understanding Molar Flow Rate

Molar flow rate refers to the amount of substance (in moles) that passes through a defined point in a system per unit of time. It's a fundamental concept in chemical engineering and thermodynamics.

Key Concepts

  • Mass Flow Rate: The mass of substance passing through a point per unit time (e.g., grams per second, kilograms per hour).
  • Molar Mass: The mass of one mole of a substance (e.g., grams per mole, kilograms per kilomole).
  • Molar Flow Rate: The number of moles of a substance passing through a point per unit time (e.g., moles per second, kilomoles per minute).

Calculation Steps

  1. Determine the Mass Flow Rate:

    • The reference video mentions an example where gaseous nitrogen flows at a rate of 150 grams per second. This is the mass flow rate.
  2. Find the Molar Mass of the Gas:

    • The molar mass is the mass of one mole of the substance. For example, the molar mass of nitrogen (N2) is approximately 28 grams per mole. You can find molar masses in the periodic table or reference books.
  3. Apply the Formula:

    • The formula to calculate the molar flow rate (ṅ) is:

      ṅ = ṁ / M

      Where:

      • ṅ is the molar flow rate (e.g., mol/s).
      • ṁ is the mass flow rate (e.g., g/s).
      • M is the molar mass (e.g., g/mol).

Example Calculation

Let's calculate the molar flow rate of the nitrogen in the example from the reference.

  • Given:

    • Mass flow rate (ṁ) = 150 grams per second.
    • Molar mass of nitrogen (N2) (M) ≈ 28 grams per mole.
  • Calculation:

    ṅ = 150 g/s / 28 g/mol

    ṅ ≈ 5.36 mol/s

  • Result: The molar flow rate of nitrogen is approximately 5.36 moles per second.

Units and Conversion

Be mindful of units and consistency in your calculations. Ensure that the units of mass flow rate and molar mass are compatible. You may need to convert units before applying the formula. For example:

  • Convert grams to kilograms if the molar mass is in kg/kmol.
  • Convert seconds to minutes if the desired molar flow rate is in moles per minute.

Additional Considerations

  • Ideal Gas Law: Sometimes, instead of mass flow rate, you might be given volumetric flow rate along with temperature and pressure. In such cases, the Ideal Gas Law (PV = nRT) can help you derive the molar flow rate.

  • Real Gases: The Ideal Gas Law might not be accurate at high pressures and low temperatures. In those situations, using real gas equations of state or compressibility factors might be necessary.

Summary

Calculating molar flow rate involves dividing the mass flow rate of the gas by its molar mass, ensuring consistent units. This concept is crucial for chemical process analysis and design.

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