Popcorn kernels get hard due to their specific composition, which includes a dense, starchy endosperm and a tough outer hull called the pericarp.
Here's a breakdown of the process:
- Starchy Endosperm: The inside of a popcorn kernel primarily consists of a hard, starchy substance called the endosperm. This endosperm contains a small amount of moisture.
- Pericarp (Hull): The endosperm is enclosed by a hard, relatively impermeable outer layer known as the pericarp or hull. This hull is crucial for the popping process.
- Drying Process: As the popcorn kernels dry during harvesting and storage, the moisture content within the endosperm decreases. However, the pericarp prevents complete dehydration, ensuring that some moisture remains trapped inside.
- Hardening: The combination of the hard, dense starch and the firm pericarp creates the characteristic hardness of unpopped popcorn kernels. This hardness is necessary to withstand the initial heating process without bursting prematurely.
In essence, the hard pericarp traps moisture within the dense, starchy endosperm, resulting in the hard texture of the kernel. This hardness is essential for the kernel to build up enough pressure internally during heating to eventually pop.