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What is the relationship between pressure and volume at constant temperature?

Published in Gas Laws 3 mins read

At constant temperature, the pressure and volume of a gas are inversely proportional. This fundamental principle is described by Boyle's Law.

According to Boyle's Law (also known as Mariotte's law), when the temperature of a gas remains constant, the pressure exerted by the gas is inversely proportional to the volume it occupies. This means that if you increase the volume of a gas while keeping the temperature constant, the pressure will decrease proportionally. Conversely, if you decrease the volume, the pressure will increase.

Mathematically, this relationship can be expressed as:

P₁V₁ = P₂V₂

Where:

  • P₁ = Initial Pressure
  • V₁ = Initial Volume
  • P₂ = Final Pressure
  • V₂ = Final Volume

This equation highlights that the product of pressure and volume remains constant at a fixed temperature. This principle is a cornerstone of gas behavior and has numerous practical applications.

Understanding Boyle's Law:

  • Inverse Proportionality: The key takeaway is that as one variable (pressure or volume) increases, the other decreases proportionally, maintaining a constant product.
  • Constant Temperature is Crucial: Boyle's Law is only valid when the temperature of the gas remains constant. Changes in temperature will affect the relationship between pressure and volume.

Examples and Applications:

  • Syringe: When you pull back on the plunger of a syringe, you increase the volume inside, which decreases the pressure. This pressure difference allows fluid to be drawn into the syringe.
  • Diving: As a diver descends deeper into the water, the pressure increases. According to Boyle's Law, the volume of air in the diver's lungs decreases. This is why divers need to equalize the pressure in their ears and sinuses.
  • Internal Combustion Engines: In the cylinders of an internal combustion engine, the compression stroke reduces the volume of the air-fuel mixture, which increases the pressure and temperature, leading to combustion.

Visual Representation:

A graph of pressure versus volume at constant temperature would show a hyperbola, illustrating the inverse relationship. As volume increases along the x-axis, pressure decreases along the y-axis, and vice versa.

Practical Insights:

Understanding Boyle's Law is essential in fields like:

  • Engineering: Designing systems involving gases, such as pneumatic systems or gas storage tanks.
  • Medicine: Understanding respiratory mechanics and gas exchange in the lungs.
  • Chemistry: Calculating gas volumes and pressures in chemical reactions.
Feature Description
Law Name Boyle's Law (or Mariotte's Law)
Relationship Pressure and Volume are inversely proportional at constant temperature.
Equation P₁V₁ = P₂V₂
Condition Constant Temperature

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