To add a Google account to your Google Drive, follow these steps using the Drive for desktop application:
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Click on the Drive for desktop icon. This is usually found in your system tray (Windows) or menu bar (macOS).
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Click on Settings Preferences. This option is often represented by a gear icon or a menu labeled "Settings" or "Preferences."
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Click on your Google account icon and on the menu, select Add another account. This will prompt you to sign in to the new Google account you want to add.
After completing these steps, you'll be able to access files from both Google accounts through the Drive for desktop application. You'll likely see both accounts listed and be able to switch between them.