Yes, humans generally have unique faces.
Humans rely heavily on visual recognition, and as a result, our faces have evolved to be individually unique. This uniqueness aids in social interaction and individual identification. While identical twins share nearly identical DNA, subtle differences in gene expression and environmental factors during development lead to variations in their facial features, making even their faces distinguishable, albeit with difficulty. The complexity of human facial structure, involving bone structure, muscle arrangement, skin texture, and even minor imperfections, contributes to this uniqueness.
Although algorithms can achieve high accuracy in facial recognition, it's important to note that even these sophisticated systems aren't foolproof, especially when dealing with similar-looking individuals. Human perception, while generally reliable, can also be subject to errors.