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How Does Pyrite Grow in Cubes?

Published in Mineral Crystallography 3 mins read

Pyrite grows in cubes because its fundamental chemical structure, made up of one iron molecule, Fe, and two sulphur molecules, S, naturally combines to form this specific geometric shape. These then combine to form the cubic structure. This means a single pyrite crystal inherently forms a perfect cube.

Understanding Pyrite's Cubic Formation

The formation of perfect cubic pyrite crystals is a fascinating natural process driven by its internal atomic arrangement.

The Role of Chemical Composition

As highlighted, pyrite has the chemical formula FeS₂. This formula indicates its composition:

  • Fe: Iron (one atom per formula unit)
  • S₂: Sulfur (two atoms per formula unit)

These atoms are not randomly arranged. Within a pyrite crystal, they are bonded together in a highly ordered, repeating pattern. This specific arrangement, dictated by the nature of the chemical bonds and the relative sizes of the iron and sulfur atoms, results in a structure that has cubic symmetry at the atomic level.

From Atoms to Macro-Crystals

Imagine building a large structure using specific types of Lego bricks. If those bricks are designed to fit together in a particular way that naturally creates cubes, then stacking many of them would result in a larger cubic structure.

Similarly, the FeS₂ "building blocks" are arranged in a lattice structure where the iron and sulfur atoms position themselves at specific points in a repeating cubic pattern. When many of these unit structures combine and stack during crystal growth, they extend this internal cubic symmetry outwards, resulting in a macroscopic crystal that exhibits cube faces.

Key takeaway: The cubic shape isn't an external coating or molding; it's a direct reflection of the ordered arrangement of iron and sulfur atoms within the crystal lattice.

How Crystal Growth Occurs

Pyrite crystals typically grow from fluids (like hydrothermal solutions) or from molten rock where the necessary iron and sulfur atoms are present. As conditions like temperature and pressure change, the atoms come out of solution and begin to bond together, adding to the growing crystal face by face. Because the underlying structure is cubic, the atoms preferentially deposit in a way that maintains and extends the cubic shape.

Factor Influence on Cubic Growth
Chemical Formula (FeS₂) Dictates the internal atomic arrangement.
Atomic Arrangement Forms a repeating cubic lattice structure.
Crystal Growth Process Extends the internal cubic structure outwards.

Examples of Cubic Pyrite

You can find examples of cubic pyrite crystals in various geological settings around the world. Navajún, Spain, for instance, is famous for producing some of the most geometrically perfect, naturally formed cubic pyrite crystals. These crystals demonstrate how well the underlying atomic structure translates into macroscopic form.

In summary: Pyrite grows in cubes because its specific chemical composition (FeS₂) leads to an internal atomic structure that is cubic. As the crystal forms by adding more iron and sulfur atoms, this internal cubic symmetry is expressed outwardly, resulting in the characteristic cube shape.

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