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How Does Natural Rubber Work?

Published in Natural Rubber Processing 2 mins read

Natural rubber works by starting as a liquid from a tree and then being processed through heat and air, ultimately becoming useful and elastic through a specific heating process called vulcanization.

Understanding Natural Rubber

Natural rubber begins its journey as a milky liquid called latex, which is extracted from the sap of certain trees, most notably the rubber tree. This material is a type of polymer, meaning it's made up of long chains of repeating molecular units.

From Sap to Solid: The Initial Steps

According to information from May 18, 2018, the process involves collecting this sap and then exposing it to mild heat and air.

This initial treatment results in a material that is natural rubber, but in a state that is described as very hard. While this hard form might have some applications, its most widely known and useful properties, such as flexibility and elasticity, are not yet fully realized.

Unlocking Elasticity: The Role of Vulcanization

To transform this hard material into the soft, elastic substance we commonly associate with rubber products, a crucial step called vulcanization is required. This process involves heating the rubber with sulfur.

Vulcanization is the key to giving natural rubber its remarkable properties:

  • Increased Elasticity: The sulfur atoms create cross-links between the long polymer chains. This allows the chains to stretch and then snap back to their original positions, providing elasticity.
  • Improved Strength and Durability: The cross-links also make the material stronger and more resistant to wear, tear, and chemical damage.
  • Temperature Stability: Vulcanized rubber maintains its properties over a wider range of temperatures compared to untreated rubber.

Essentially, the process described in the reference highlights a two-stage transformation:

  1. Stage 1: Sap to Hard Rubber (via mild heat and air)
  2. Stage 2: Hard Rubber to Soft & Elastic Rubber (via vulcanization with sulfur)

This processing, particularly the vulcanization step, is how natural rubber is made "to work" effectively in various applications, enabling it to stretch, bend, and recover its shape repeatedly.

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