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Is Nitrogen Dioxide Soluble in Water?

Published in Nitrogen Dioxide Solubility 2 mins read

Yes, nitrogen dioxide is soluble in water.

Understanding Nitrogen Dioxide (NO₂)

Nitrogen dioxide (NO₂) is a reddish-brown toxic gas with a pungent odor. It is a significant air pollutant, primarily produced from the combustion of fossil fuels in vehicles and power plants. Its presence in the atmosphere has various environmental impacts.

Solubility of NO₂ in Water

Based on information regarding the solubility of Nitrogen dioxide in Water, this gas readily dissolves when it comes into contact with water. However, the process is not just simple dissolution; it involves a chemical reaction.

The Chemical Reaction

When nitrogen dioxide dissolves in water, it undergoes a disproportionation reaction, forming two different acids: nitrous acid (HNO₂) and nitric acid (HNO₃).

The primary reaction can be represented as:

2 NO₂(g) + H₂O(l) → HNO₂(aq) + HNO₃(aq)

  • (g) denotes gas
  • (l) denotes liquid
  • (aq) denotes aqueous solution (dissolved in water)

Nitrous acid (HNO₂) is unstable, especially at higher concentrations or temperatures, and can further decompose or react. Nitric acid (HNO₃) is a strong acid.

Implications of NO₂ Solubility

The solubility of nitrogen dioxide in water has important environmental consequences:

  • Acid Rain Formation: When NO₂ dissolves in atmospheric moisture (like clouds, fog, or rain droplets), it forms nitric acid. This nitric acid contributes significantly to acid rain, which can harm ecosystems, damage buildings and infrastructure, and acidify lakes and streams.
  • Respiratory Health: NO₂ can dissolve in the moisture lining the respiratory tract, forming acids that can irritate and damage lung tissue.

In summary, while the gas doesn't just passively mix like salt in water, it chemically reacts with water, confirming its solubility and highlighting its role in environmental processes like acid rain.

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