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How Does Increased Ocean Acidity Affect Calcium Carbonate Formation?

Published in Ocean Acidification Effects 3 mins read

Increased ocean acidity significantly disrupts the formation of calcium carbonate, a vital building block for many marine organisms.

Ocean acidification, a direct consequence of increased atmospheric carbon dioxide being absorbed by the oceans, makes the water more acidic. As stated in the provided reference, this process is "disrupting the formation of calcium carbonate in sea life and disturbing their homeostasis."

The Impact on Calcium Carbonate Formation

Calcium carbonate (CaCO₃) is a mineral compound used by numerous marine creatures to build their shells, skeletons, and other hard structures. When ocean waters become more acidic, the concentration of carbonate ions, which are essential for organisms to form calcium carbonate, decreases. This makes it more difficult for marine life to synthesize their protective or structural elements.

Effectively, the increased acidity:

  • Reduces Availability of Building Blocks: Lower carbonate ion availability slows down or prevents the formation of calcium carbonate.
  • Can Lead to Dissolution: In severely acidic conditions, existing calcium carbonate structures can weaken and even dissolve.

Why is Calcium Carbonate Formation Crucial?

Many organisms rely on calcium carbonate for survival and function. Its disruption impacts entire ecosystems.

Organisms Affected by Impaired Calcium Carbonate Formation

A wide variety of marine life are vulnerable, including:

  • Shellfish: Oysters, clams, mussels, and scallops use CaCO₃ for their shells. Difficulty forming shells makes them more susceptible to predators and environmental stress.
  • Corals: Coral reefs are built from calcium carbonate skeletons produced by polyps. Weakened structures make reefs fragile and vulnerable to erosion, impacting the diverse life they support.
  • Plankton: Tiny marine organisms like pteropods (sea butterflies) and foraminifera, which form the base of many food webs, have calcium carbonate shells. Their decline affects species higher up the chain.
  • Crustaceans: Crabs, lobsters, and other crustaceans use calcium carbonate to harden their exoskeletons after molting.

This disruption not only threatens individual species but also disturbs the complex balance and interconnectedness of marine ecosystems, affecting biodiversity and potentially collapsing food webs. The reference highlights this broader impact by mentioning the disturbance of "their homeostasis," which refers to the ability of organisms to maintain stable internal conditions necessary for survival.

The Mechanism

The simplified chemical process involves carbon dioxide (CO₂) reacting with water (H₂O) to form carbonic acid (H₂CO₃). Carbonic acid then releases hydrogen ions (H⁺), increasing acidity (lowering pH), and bicarbonate ions (HCO₃⁻). These reactions reduce the availability of carbonate ions (CO₃²⁻), which marine organisms need to combine with calcium ions (Ca²⁺) to form CaCO₃.

Component Role in Calcification Effect of Acidification
Calcium Ions (Ca²⁺) Available in seawater Generally unchanged by acidification
Carbonate Ions (CO₃²⁻) Combines with Ca²⁺ to form CaCO₃ Reduced availability due to acidification
Hydrogen Ions (H⁺) Indicates acidity Increased concentration due to acidification

This table illustrates how the critical component for calcium carbonate formation (carbonate ions) becomes less available as hydrogen ions increase due to acidification.

Understanding how increased acidity disrupts calcium carbonate formation underscores the significant threat ocean acidification poses to marine life and the health of the global ocean.

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