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Is Carbon Dioxide a Solute in Sea Water?

Published in Ocean Chemistry 2 mins read

Yes, carbon dioxide is indeed a solute in seawater.

While carbon dioxide is often thought of as a gas, it dissolves in seawater and undergoes chemical reactions that transform it into other forms. According to the provided reference, carbon dioxide is the most soluble gas in seawater. This means that it readily enters the water from the atmosphere and becomes part of the solution.

Forms of Carbon Dioxide in Seawater

It's important to note that carbon dioxide doesn't exist in seawater solely as the gas CO2. Instead, it primarily exists as:

  • Bicarbonate ions (HCO3-): This is the most abundant form of dissolved inorganic carbon in seawater.
  • Carbonate ions (CO32-): Another major component of dissolved inorganic carbon.

The interaction between carbon dioxide and water is described by the following reaction:

CO2 + H2O ⇌ H2CO3 ⇌ HCO3- + H+ ⇌ CO32- + 2H+

This reaction shows that carbon dioxide reacts with water to form carbonic acid (H2CO3), which quickly dissociates into bicarbonate and then carbonate ions.

Solubility of Gases in Seawater

Gas Solubility in Seawater Notes
Carbon Dioxide High Most soluble gas, mainly present as bicarbonate and carbonate ions.
Oxygen Lower Can become supersaturated in surface waters.

Implications

Understanding how carbon dioxide behaves in seawater is crucial because:

  • It plays a significant role in ocean acidity.
  • It's part of the global carbon cycle.
  • It affects marine ecosystems.

Therefore, while the term "solute" typically makes us think of dissolved solids, it also applies to gases like carbon dioxide when they become part of a liquid solution like seawater.

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