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What is the General Formula for Carboxylic Acid?

Published in Organic Chemistry Formulas 2 mins read

The general formula for a carboxylic acid is R−COOH.

Carboxylic acids are a class of organic compounds characterized by a carboxyl functional group, which has the formula -COOH. This group consists of a carbonyl group (C=O) and a hydroxyl group (O-H) bonded to the same carbon atom.

Understanding the Formula

The general formula R−COOH clearly shows the structure:

  • R: This represents the rest of the molecule. According to the reference, R can be:
    • An organyl group (like an alkyl, alkenyl, or aryl group).
    • Hydrogen (H). When R is H, the molecule is formic acid (HCOOH), the simplest carboxylic acid.
    • Other groups.
  • −COOH: This is the carboxyl group, the defining functional group of carboxylic acids.

Alternative Representations

The reference also mentions other ways the general formula is sometimes written:

  • R−CO₂H: This is a more compact way of writing R−COOH, indicating one carbon atom, two oxygen atoms, and one hydrogen atom in the functional group.
  • R−C(O)OH: This representation explicitly shows the carbonyl C=O bond within the carboxyl group, emphasizing the structure more than the compact R−CO₂H.

Examples of 'R' Groups

The nature of the 'R' group determines the specific carboxylic acid.

  • Alkyl Group: If R is a methyl group (CH₃), the acid is acetic acid (CH₃COOH).
  • Hydrogen: If R is Hydrogen (H), the acid is formic acid (HCOOH).
  • Aryl Group: If R is a phenyl group (C₆H₅), the acid is benzoic acid (C₆H₅COOH).

Structure Breakdown (R-COOH)

Here's a simple breakdown of the common R-COOH formula:

Part Description Notes
R Represents a hydrogen or an organic group (e.g., hydrocarbon chain, ring) Determines the specific acid
Single bond Connects R to the carboxyl group
C Carbon atom Central atom of the carboxyl group
=O Carbonyl group Carbon double-bonded to oxygen
−OH Hydroxyl group Oxygen single-bonded to hydrogen

In essence, the R−COOH formula captures the core structure where any variety of organic substituent (or hydrogen) is attached to the characteristic carboxyl functional group.

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