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What is Mendeleev's Law?

Published in Periodic Law 3 mins read

Mendeleev's law states that the properties of chemical elements show a periodic relationship with their atomic masses.

Understanding Mendeleev's Periodic Law

Dmitri Mendeleev, a Russian chemist, formulated his periodic law, which is a cornerstone in the development of the modern periodic table. His law essentially means that if elements are arranged in order of increasing atomic mass, elements with similar chemical and physical properties would appear at regular (periodic) intervals.

Key Aspects of Mendeleev's Law

  • Atomic Mass as the Basis: Mendeleev used the atomic mass of elements as the primary criterion for their arrangement. This was a significant step as it showed an underlying pattern linking elements.
  • Periodic Nature: The recurrence of similar properties at certain intervals is what makes it a periodic law. It is because of this periodicity that we call it the periodic table.
  • Predictive Power: By noticing gaps in his periodic arrangement, Mendeleev was able to predict the existence and properties of then-unknown elements, showcasing the predictive power of his law.
    • For example, he predicted the properties of "eka-aluminum" which was later discovered to be gallium.
  • Ordering Principle: The law provided a systematic way to organize the known elements, making it easier to understand their behavior and relationships.

Differences with Modern Periodic Law

While Mendeleev's periodic law was revolutionary, the modern periodic law uses atomic number, not atomic mass, as the ordering principle. This revision corrects some inconsistencies found in Mendeleev's table.

Aspect Mendeleev's Law Modern Periodic Law
Ordering Principle Atomic Mass Atomic Number
Basis for Periodicity Properties are periodic with atomic mass Properties are periodic with atomic number
Accuracy in the Table Less accurate in certain placements More accurate

Impact of Mendeleev's Law

Mendeleev's law was transformative, shaping our understanding of chemical elements and their behaviors:

  • Foundation for Chemistry: It served as a foundation for modern chemical classification.
  • Organized Learning: By classifying chemical elements, it simplified the learning of complex chemical properties and reactions.

In conclusion, Mendeleev's periodic law is that the physical and chemical properties of elements are a periodic function of their atomic masses. This crucial concept led to the development of the modern periodic table we use today.

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