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How is ABS Made?

Published in Polymer Manufacturing 3 mins read

ABS, or Acrylonitrile Butadiene Styrene, is created through a specific chemical process. It involves a few key elements working together to form this strong and versatile plastic.

The ABS Manufacturing Process

The core method for making ABS involves polymerization. In essence, this means joining small molecules (monomers) into large chains (polymers). Here’s a breakdown of the main approach, as explained in the provided reference:

  • Polymerization with Polybutadiene: ABS is typically manufactured by polymerizing styrene and acrylonitrile. This is done when a chain of polybutadiene is already present.

    • Think of polybutadiene as the backbone.
    • Styrene and acrylonitrile are then attached to this backbone.
  • Emulsion Polymerization: Another method used is emulsion polymerization. This involves mixing the monomers with an emulsifier to form small droplets in water, and then polymerizing them, as highlighted by the reference that mentions that ABS is made via "emulsion or by polymerizing styrene and acrylonitrile in the presence of polybutadiene."

Key Components and Their Roles

The unique properties of ABS come from the combination of three monomers:

  • Acrylonitrile: This contributes to the chemical resistance and strength of the plastic.
  • Butadiene: This is a rubbery substance that provides impact strength and flexibility. This substance makes the material tough and durable.
  • Styrene: This adds rigidity and makes the plastic easy to mold and process.

The Resulting Structure

The combination of these components results in a unique structure:

  • Crisscrossing Chains: The long chain of polybutadiene is crisscrossed with shorter chains of polystyrene-co-acrylonitrile.
  • Strong Bonds: These crisscrossing chains create strong bonds, giving ABS its high impact resistance, toughness, and durability.

Practical Insights

  • The process results in a material that is a thermoplastic. This means it can be heated and reshaped multiple times, making it ideal for recycling.
  • ABS is widely used in automotive parts, electronic housings, and toys because of this combination of properties.

Summary

In summary, ABS is made by polymerizing styrene and acrylonitrile in the presence of polybutadiene. This creates a network of long and short molecular chains which give the material its unique strength, toughness and chemical resistance. The process may be conducted via emulsion polymerization.

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