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How do secondary cell batteries work?

Published in Rechargeable Batteries 2 mins read

Secondary cell batteries, also known as accumulators, work by storing energy in a chemical form and then converting that chemical energy back into electrical energy when needed. This makes them rechargeable.

Understanding the Process

Here's a breakdown of how secondary batteries function:

  • Energy Storage: Secondary batteries store electrical energy as chemical energy. During the charging process, an external electrical source forces a chemical reaction within the battery. This reaction stores energy by creating chemical compounds that have a higher energy state.
  • Energy Conversion: When the battery is used (discharging), the chemical reaction reverses. The chemical compounds formed during charging react to release electrical energy, which can then power a device.
  • Reversibility: The key feature of secondary batteries is the reversibility of the chemical reactions. This allows the battery to be repeatedly charged and discharged.

Chemical Reactions: The Heart of the Battery

The specific chemical reactions vary depending on the type of secondary battery. Here are a few common examples:

Battery Type Charging Discharging
Lead-Acid Lead sulfate is converted to lead and lead dioxide. Lead and lead dioxide react to form lead sulfate.
Lithium-ion (Li-ion) Lithium ions move from the cathode to the anode and are stored in the anode material Lithium ions move from the anode to the cathode, releasing energy to power the battery.
Nickel-Metal Hydride (NiMH) Nickel hydroxide is oxidized at the positive electrode, and hydrogen is stored in the negative electrode. Nickel hydroxide is reduced at the positive electrode, and hydrogen is released from the negative electrode.

Practical Insights

  • Charging: Proper charging techniques are crucial for maximizing the lifespan and performance of secondary batteries. Overcharging or deep discharging can damage the battery.
  • Applications: Secondary batteries are used in a wide range of applications, including:
    • Mobile phones
    • Laptops
    • Electric vehicles
    • Power tools
    • Uninterruptible power supplies (UPS)

Summary

Secondary batteries provide reusable power by converting electrical energy into stored chemical energy, then back into electrical energy when needed, through reversible chemical reactions.

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