Many actresses have served as UNICEF Ambassadors or Goodwill Ambassadors. There is no single answer to this question. Several prominent actresses have held this role, each contributing significantly to UNICEF's mission.
Here are some examples:
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Audrey Hepburn: An internationally renowned actress, Audrey Hepburn was a tireless advocate for children's rights as a UNICEF Goodwill Ambassador from 1988 until her death. https://www.unicef.org/goodwill-ambassadors/audrey-hepburn
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Alyssa Milano: A UNICEF Ambassador since 2003, Alyssa Milano is known for her roles in "Who's the Boss?" and "Charmed." https://www.unicefusa.org/about-unicef-usa/partnerships/our-supporters/celebrities/alyssa-milano
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Millie Bobby Brown: In 2018, Millie Bobby Brown became UNICEF's youngest-ever Goodwill Ambassador. https://www.unicef.org/goodwill-ambassadors/millie-bobby-brown
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Priyanka Chopra: Priyanka Chopra served as a UNICEF National Ambassador, promoting children's rights. https://news.un.org/en/story/2010/08/347422
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Selena Gomez: Selena Gomez has been a UNICEF Ambassador since 2009. https://www.unicefusa.org/about-unicef-usa/partnerships/our-supporters/celebrities/selena-gomez
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Aria Mia Loberti: A newly appointed UNICEF Ambassador. https://www.unicefusa.org/stories/6-questions-unicef-ambassador-aria-mia-loberti
These are just a few examples; many other actresses have contributed to UNICEF's work. The specific actress who is the "UNICEF ambassador actress" depends on the timeframe and the specific type of ambassadorial role.