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How to Calculate Oxygen Saturation in Water?

Published in Water Chemistry 4 mins read

To calculate oxygen saturation in water using a saturation scale chart, draw a line connecting the water temperature value to the measured dissolved oxygen value. The point where the line intersects the saturation scale indicates the percent oxygen saturation.

Here's a breakdown of the process and considerations:

Understanding Oxygen Saturation

Oxygen saturation in water refers to the relative amount of dissolved oxygen (DO) present compared to the maximum amount the water can hold at a specific temperature and pressure. It's expressed as a percentage. 100% saturation means the water is holding as much oxygen as it possibly can under those conditions.

Methods for Determining Oxygen Saturation

While the quick method using a saturation scale is useful, several other techniques exist:

  • Using a Dissolved Oxygen Meter (DO Meter): This is the most common and accurate method. A DO meter measures the concentration of dissolved oxygen in the water, and many meters also calculate the saturation percentage automatically, factoring in temperature and sometimes salinity.

  • Winkler Titration Method: This is a chemical method that involves a series of titrations to determine the dissolved oxygen concentration. You would then use temperature and pressure data to calculate the saturation percentage.

  • Using a Saturation Scale Chart (Nomograph): This graphical method involves the following steps:

    1. Measure Water Temperature: Accurately measure the temperature of the water in degrees Celsius or Fahrenheit.

    2. Measure Dissolved Oxygen (DO): Determine the dissolved oxygen concentration in milligrams per liter (mg/L) or parts per million (ppm). A DO meter or the Winkler titration method can be used.

    3. Use the Saturation Scale Chart:

      • Most charts have three scales: temperature, dissolved oxygen concentration, and oxygen saturation percentage.
      • Locate the measured temperature on the temperature scale.
      • Locate the measured dissolved oxygen concentration on the DO scale.
      • Draw a straight line connecting these two points.
      • The point where the line intersects the saturation scale gives you the oxygen saturation percentage.

Factors Affecting Oxygen Saturation

Several factors influence the amount of oxygen that can dissolve in water:

  • Temperature: Colder water holds more oxygen. As temperature increases, oxygen solubility decreases.
  • Pressure: Higher pressure increases oxygen solubility.
  • Salinity: Saltwater holds less oxygen than freshwater.
  • Altitude: At higher altitudes, lower atmospheric pressure reduces the amount of oxygen that can dissolve in the water.

Example

Let's say you measure a water sample with a temperature of 20°C and a dissolved oxygen concentration of 8 mg/L. Using a saturation scale chart, you would draw a line connecting 20°C on the temperature scale to 8 mg/L on the DO scale. If that line intersects the saturation scale at 90%, then the oxygen saturation of the water is 90%.

Importance of Oxygen Saturation

Monitoring oxygen saturation is crucial for:

  • Aquatic Life: Oxygen is essential for the survival of fish, invertebrates, and other aquatic organisms.
  • Water Quality Assessment: Low oxygen levels can indicate pollution or other environmental problems.
  • Wastewater Treatment: Oxygen is needed for the biological processes that break down pollutants in wastewater.
  • Aquaculture: Maintaining proper oxygen levels is essential for healthy fish growth in aquaculture systems.

In summary, calculating oxygen saturation in water involves determining the relative amount of dissolved oxygen compared to its maximum capacity, considering temperature, pressure, and salinity. The saturation scale chart provides a simple graphical method, but using a DO meter offers a more direct and accurate measurement.

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