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Is H2O an Acid or Base?

Published in Water Chemistry 2 mins read

Water (H2O) is unique in that it is both an acid and a base. This property is known as being amphiprotic. According to the provided reference, water can both accept and donate hydrogen ions (H+), enabling it to act as either an acid or a base.

How Water Acts as an Acid and Base

Characteristic Acidic Role Basic Role
Action Donates a hydrogen ion (H+) Accepts a hydrogen ion (H+)
Result Forms a hydroxide ion (OH-) Forms a hydronium ion (H3O+)
Description Acts as a proton donor Acts as a proton acceptor
Example Reaction H2O + NH3 ⇌ OH- + NH4+ (water donates H+) H2O + HCl ⇌ H3O+ + Cl- (water accepts H+)

Understanding Amphiprotic Nature

  • Self-ionization: Water can undergo self-ionization, a process where one water molecule donates a proton to another, forming hydronium (H3O+) and hydroxide (OH-) ions. This shows its ability to act both as an acid and a base in the same reaction.
  • Dynamic Equilibrium: In pure water, the concentrations of H3O+ and OH- are equal, making it neutral. This dynamic equilibrium constantly shifts as other substances are added.

Examples and Practical Insights

  • Acidic Solutions: When acids are added to water, they donate H+ ions, increasing the concentration of H3O+ ions and making the solution acidic. In these scenarios, water acts as a base by accepting these ions.
  • Basic Solutions: When bases are added to water, they accept H+ ions, increasing the concentration of OH- ions and making the solution basic. In these cases, water acts as an acid by donating H+ ions.
  • pH Scale: The pH scale measures the acidity or basicity of a solution. Pure water has a pH of 7, indicating a neutral solution with equal concentrations of H3O+ and OH- ions.

Therefore, because H2O can act as both a proton donor and a proton acceptor, it's considered both an acid and a base. Its amphiprotic nature is fundamental in many chemical reactions and biological processes.

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