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What Causes Surface Tension in Water?

Published in Water Properties 2 mins read

Water's high surface tension is primarily due to the strong hydrogen bonds between its molecules. Each water molecule is attracted to its neighboring molecules, creating a cohesive force. This attraction is stronger at the surface of the water, where molecules are not completely surrounded by other water molecules. This imbalance of attractive forces results in the surface acting like a stretched elastic membrane.

Understanding Hydrogen Bonds

The unique structure of water, with its polar nature (oxygen being slightly negative and hydrogen slightly positive), allows for the formation of hydrogen bonds. These bonds are relatively strong compared to other intermolecular forces, significantly contributing to water's high surface tension. As stated in multiple sources, "Consequently, an electrostatic attraction occurs between the hydrogen atom in one water molecule and the oxygen atom in another. These bonds are referred to as hydrogen bonds, which engender robust cohesive forces among water molecules, ultimately resulting in the high surface tension observed in water." (Source 1) Another source explains that "Surface tension in water owes to the fact that water molecules attract one another, as each molecule forms a bond with the ones in its vicinity." (Source 2, 5)

Practical Implications of Surface Tension

The high surface tension of water has numerous practical implications:

  • Water droplets: Water forms spherical droplets due to the minimization of surface area caused by surface tension.
  • Capillary action: Water climbs up thin tubes against gravity due to the cohesive forces between water molecules and the adhesive forces between water and the tube's surface.
  • Insect locomotion: Some insects can walk on water due to surface tension supporting their weight.

In Summary

The cohesive forces resulting from hydrogen bonding between water molecules are the primary cause of water's high surface tension. This phenomenon has significant impacts on various natural and man-made processes.

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